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A-level化学知识点梳理系列(十五)

来源:渊学通      发布时间:

有机化学(一):基本概念
  有机化学是化学的一个非常重要的分支,也是A-level考试的重点考察对象。这一领域入门比较困难,和之前学到的化学知识没有太多联系,而且学完以后往往没有多少时间消化就要准备迎接考试。对于有机化学,大家一定要克服畏难情绪,勤加记忆,多加练习,就能在有机这一块拿到高分。
   一、有机分子的表示方式
empirical formula
molecular formula
structural formula CH3CH=CH2
displayed formula
skeletal formula
   二、官能团

functional group structure general formula name
alkene ethene
arene benzene
halogeno-alkane chloromethane
alcohol methanol
aldehyde ethanal
ketone propanone
carboxylic acid ethanoic acid
ester ethyl ethanoate
amine methylamine
nitrile    ethanenitrile

       三、有机分子的命名

no. of carbon atomname of alkane
1methane
2ethane
3propane
4butane
5pentane
6hexane
7heptane
8octane
9nonane
10decane

 

       1. Number the carbon atoms in the longest chain.
       2. The numbering starts at the end that produces the lowest possible numbers in the name.
       3. The hydrocarbon side-chain is named by adding yl to the normal alkane stem. This type of group is called an alkyl group.
       4. If there is more than one of the same alkyl side-chain, we indicate how many by inserting di, tri, tetra in front of its name.
       5. If there is more than one type of alkyl side-chain, they are listed in alphabetical order.
       6. In an alkene or alkyne, the longest carbon chain is numbered from the end that gives first carbon of the double/triple bond the lowest possible number.
       四、有机分子中的化学键
       sigma bond         sp3 orbital hybridization
       pi bond                sp2 orbital hybridization
       五、同分异构体
       1、structural isomerism
         functional group isomerism
              alkene - cycloalkane
              alcohol - ether
              aldehyde - ketone
              carboxylic acid  ester
         chain isomerism
         position isomerism
       2、 stereoisomerism
         cis-trans
         optical
       下面我们来看一道真题。
       s12-qp12
       
       解析:这道题考察的是有机分子的命名法。从penta-可以看出有5个碳原子,排除C和D,再从2号碳原子连氯原子,3号碳原子连-OH可以判断正确答案是A。

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